2-Ethyl-3,5,6-triphenylpyrazine
نویسندگان
چکیده
In the title mol-ecule, C(24)H(20)N(2), the pyrazine ring is significantly distorted from planarity, presumably due to steric crowding, and its conformation is well described as a flattened twist-boat. The benzene ring adjacent to the ethyl group forms dihedral angles of 53.79 (13) and 85.47 (12)° with the other benzene rings; the dihedral angle between adjacent benzene rings is 57.90 (12)°. The ethyl group is disordered over two positions; the site-occupancy factor of the major component is 0.546 (4). No hydrogen bonds are found in the crystal structure.
منابع مشابه
4,5,6-Tri-O-acetyl-2,3-di-S-ethyl-2,3-dithio-d-allose diethyl dithioacetal
The title compound, C(20)H(36)O(6)S(4), was obtained by ethanethiol-ysis of 3,5,6-tri-O-acetyl-1,2-O-isopropyl-idene-α-d-gluco-furan--ose. One of the ethyl groups is disordered over two sites with refined occupancies of 0.869 (6) and 0.131 (6). Compared with the precursor, the absolute configuration of the stereocenters at positions C-3 and C-2 are inverted and maintained, respectively.
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